International Symposium on Technetium and Rhenium
Science and Utilization
(Senday, Moscow, Shizuoka, Dubna, O-arai, Port-Elizabeth, Moscow, Pornichet, Sydney, Moscow, Karlsruhe-2020)
(ISTR)

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The Third Russian-Japanese Seminar on Technetium ToSee

June 24 (Monday)

 12:00 13:30         Registration   (House of International Conferences)

 15:00 15:20         Opening          (Chairpersons:  G.Kodina, T.Sekine)

 

15:20 15:50         Born to burn (Tc-99 fate as regarded during last 40 years)

                                K.German, V. Peretrukhin, A. Kozar                               See: Born to burn - PPS

(Laboratory of Radiochemical Researches of Institute of Physical Chemistry, RAS, Moscow, Russia, e-mail: german@ipc.rssi.ru )

 

Analytical and environmental chemistry of technetium

 

Chairpersons:   B.Myasoedov, T.Omori

 

2401          (16:10 16:30) Time dependence on plant availability of technetium in soils. K.Tagami, S.Uchida

                  PDF Tc in soils

K.Tagami, S.Uchida (Environmental and Toxicological Sciences Research Group, National Institute of Radiological Sciences, Japan)

 

2402                    (16:30 16:50) Bioaccumulation of Tc-99, Pu-239 and Np-237 by bottom sediments f freshwhater lakes of Moscow Region

Bioaccumulation of Tc-99, PDF

K.German, E.Firsova, V.Peretrukhin, T.Khijnyak. M.Simonoff (Institute of Physical Chemistry, RAS, Moscow, Russia; UMR 5084 - Chimie Nucléaire Analytique et Bioenvironnementale, Gradignan, France)    

[Presentation in PPS-format]

 

2403                    (16:50 17:20) Spatial locality in investigation of the technetium electron structure in compounds by conversion electron spectroscopy

Spatial locality in investigation of the technetium electron structure in compounds by conversion electron spectroscopy

V.Gerasimov (Institute of General and Nuclear Physics, Russian Research Center Kurchatov Institute, Moscow, Russia)

 

2404                    (17:20 17:35) Concentrating of rhenium by plants

Concentrating of rhenium by plants

L.Borisova, V.Ermakov (V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS, Moscow, Russia)

 

2405                    (17:35 17:55) Electrochemical reactions for technetium recovery and analysis in the radwastes solutions

                    A.Maslennikov, V.Peretrukhin, V.Silin, A.Kareta, V.Sladkov, F.David, B.Fourest, O.Courson, M.Masson, M.Lecomte, C.Delegard

Electrochemical reactions PDF  (Institute of Physical Chemistry, RAS, Moscow, Russia; IPN Orsay France;  CE VALRHO France; US DOE)         [Presentation in PPS-format]

  

2406                    (17:55 18:15) Application of fibrous "filled" sorbents type polyorgs for extraction of technetium (VII) from aqueous media

Application of fibrous "filled" sorbents PDF

N.Popova, I.Tananaev, G.Myasoedova, B.Myasoedov (Institute of Geochemistry and Analytical Chemistry, RAS, Moscow, Russia)                       [Presentation in PPS-format]

 

 2407                    (18:15 18:30) Sorption of technetium by new chelating sorbents based on fibrous material filled with complexing groups

Sorption of technetium PDF

I.Medvedeva, S.Rovnyi, N.Kuznetsova (Federal State Unitary Enterprise Mayak Production Assosiation, Ozersk, Russia)

 

2408                    (18:30 18:45) Determination of rhenium in extractants by inductively coupled plasma atomic emission spectrometry

I.Troshkina, Y.Deshin, A.Chekmarev, S.Konstantinov, V.harlamov (D.Mendeleyev University of Chemical Technology, Moscow, Russia)

 

2409                    (18:45 19:00) Comparative investigation of the aqueous technetium - tricarbonyl in different chromatographycal systems

PDF A.Inkin, G.Kodina, A.Malysheva, M.Khasina, D.Suglobov, N.Gorshkov (State Scientific Center - Institute of Biophysics, Moscow; V.Khlopin Radium Institute, St.-Petersburg, Russia)

 

June 25 (Tuesday)

  

Coordination chemistry of technetium and rhenium

                 

Chairpersons:   D.Suglobov, T.Sekine

 

2501                    (9:30 9:50) Quantum-chemical study of acetate binuclear Tc cluster

PDF - Tc cluster Yu.Plekhanov, K.German, R.Sekine (Institute of Physical Chemistry,RAS, Moscow, Russia; Shizuoka University, Shizuoka, Japan)

 

2502                    (9:50 10:05) Electronic Structure of the Metallic Technetium Cluster Models using DV-Xa- calculations
Yu.Plekhanov, K.German, R.Sekine
PDF- DV-Xa- calculations

Yu.Plekhanov, K.German, R.Sekine (Institute of Physical Chemistry,RAS, Moscow, Russia; Shizuoka University, Shizuoka, Japan)

 

2503                    (10:05 10:25) Geometric and electronic structures for Mn and Tc clusters by density functional method
R.Sekine
PDF- density functional method

R.Sekine (Department of Chemistry, Faculty of Science, Shizuoka University, Shizuoka, Japan)

 

2504                    (10:25 10:45) Structure of nitridotechnetium(V) complexes with cysteine methyl ester and KYCAR
T.Takayama, S.Sato, T.Sekine, H.Kudo
PDF -  KYCAR

T.Takayama, S.Sato, T.Sekine, H.Kudo (Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Japan)

 

                   Chairpersons:   M.Grigoriev, R.Sekine

 

2505                    (11:10 11:30) Base hydrolysis reaction of dichloroethoxyoxobis(tri-phenylphosphine) rhenium (V)
T.Omori, Y.Hayashi, M.Kawasaki, M.Yanaga, H.Suganuma

Base hydrolysis PDF

T.Omori, Y.Hayashi, M.Kawasaki, M.Yanaga, H.Suganuma (Radiochemistry Research Laboratory, Shizuoka University, Japan)                      [Presentation in PDF-format]

2506                    (11:30 11:50) Synthesis, crystal structure and some properties of [(NpO2)(ReO4)(Phen)(H2O)2] N.Budantseva, A.Fedosseev, G.Andreev, M.Antipin PDF  [(NpO2)(ReO4)(Phen)(H2O)2]

N.Budantseva, A.Fedosseev, G.Andreev, M.Antipin (Institute of Physical Chemistry, RAS; A. N. Nesmeyanov Institute of Organoelement Compounds, RAS, Moscow, Russia)

 

2507                    (11:50 12:05) Synthesis, structure and properties of zirconium (IV) and uranyl pertechnetate and perrhenate
K.German, M.Grigoriev
- PDF

(Institute of Physical Chemistry, RAS, Moscow, Russia)

[Presentation in PPS-format]

  

2508                    (12:05 12:20) Structure and some properties of pertechnetate and perrhenate of tetrapropylammonium
M.Grigoriev, K.German, C.Den Auver, J.-Ph.Dancausse, M.Masson, M.Simonoff

PDF

M.Grigoriev, K.German, C.Den Auver, J.-Ph.Dancausse, M.Masson, M.Simonoff

(Institute of Physical Chemistry, RAS, Moscow, Russia; CEN VALRHO, Marcoule, France, UMR 5084 - Chimie Nucléaire Analytique et Bioenvironnementale, Le Haut Vigneau, Gradignan, France)

 

2509                    (12:20 12:35) The structure and properties of red pertechnetic acid in solid state and solutions as probed by NMR

                    G.Kirakosyan, K.German, M.Grigoriev, V.Tarasov

The structure and properties of red pertechnetic acid in solid state and solutions as probed by NMR

G.Kirakosyan, K.German, M.Grigoriev, V.Tarasov (Institute of Physical Chemistry, RAS, Moscow, Russia)

[Presentation in PPS-format]

  

2510                    (12:35 12:55) Ditiocarbamate based chelation units for linking M(CO)3+ (M = Tc, Re) species to other molecules
N.Gorshkov, J.Katzenellenbogen, L.Luyt, A.Lumpov, A.Miroslavov, D. Suglobov
PDF-s

N.Gorshkov, J.Katzenellenbogen, L.Luyt, A.Lumpov, A.Miroslavov, D. Suglobov (Khlopin Radium Institute, St.-Petersburg, Russia; University of Illinois, Department of Chemistry, USA)

 

Technetium in reprocessing of spent nuclear fuel

                   Chairpersons:   Dr. Vakhrushin, M.Ozawa

 

2511                    (14:15 14:35) Research activities on ruthenium and technetium chemistry in purex system organized by the Japanese Atomic Energy Society S.Matsumoto, G.Uchiyama, M.Ozawa, Y.Kobayashi, K.Shirato PDF - Research & Society

S.Matsumoto, G.Uchiyama, M.Ozawa, Y.Kobayashi, K.Shirato (Saitama-University; Japan Atomic Energy Research Institute; Japan Nuclear Cycle Development Institute; Japan Nuclear Fuel Limited,  Ishikawajima-Harima Heavy Industries Co., Ltd., Japan)

 

2512                    (14:35 14:50) Technetium behaviour during spent fuel reprocessing at PR-1 plant
A.Mashkin, E.Dzekun, D.Kolupaev, K.Korchenkin, S.Rovnyi
PDF- PR-1 plant

A.Mashkin, E.Dzekun, D.Kolupaev, K.Korchenkin, S.Rovnyi (Federal State Unitary Enterprise "Mayak" Production Assosiation, Ozyorsk, Russia)

 

2513                    (14:50 15:05)  HLW management and technetium-99 problem A.Ochkin PDF-HWL

A.Ochkin (D.Mendeleev University of chemical technology of Russia, Moscow, Russia)

 

 2514                    (15:05 15:20) 99Tc transmutation in high flux reactor SM A.Kozar, V.Tarasov, Yu.Toporov, V.Peretrukhine, V.Radchenko, E.Karelin, E. Romanov

PDF SM A.Kozar, V.Tarasov, Yu.Toporov, V.Peretrukhine, V.Radchenko,  E.Karelin, E. Romanov (Institute of Physical Chemistry, RAS, Moscow, Russia; State Scientific Center of the Russian Federation Research Institute of Atomic Reactors, Dimitrovgrad, Russia)

 

                  Chairpersons:   K. German, S.Matsumoto

 

2515                    (15:40 16:00)

Strategic separation of technetium and rare metal fission-products in spent nuclear fuel - solvent extraction behavior and partitioning by catalytic electrolytic extraction

M.Ozawa, M.Ishida, Y.Sano (Japan Nuclear Cycle Development Institute O-arai Engineering Center , Tokai Works, Japan)

 

2516                    (16:00 16:15)

Development of the technique and monitoring means for conversion of ammonia pertechnetate into technetium dioxide

V.Ershov. V.Kapitonov, M.Makarov, S.Rovnyi, V. Peretrukhin (CentraI Plant Laboratory, Federal State Unitary Enterprise "Mayak" Production Assosiation, Ozyorsk, Russia; Institute of Physical Chemistry, RAS, Moscow, Russia)

 

2517                    (16:15 16:30)

Technetium (VII) extraction by mono and bidentate neutral organophosphorus compounds from nitric solutions

N.Popova, G.Pribylova, I.Tananaev, B.Myasoedov (Institute of Geochemistry and Analytical Chemistry,RAS, Moscow, Russia)           [Presentation in PPS-format]

 

2518                    (16:30 16:45)

Extraction technology of recovered uranium purification from technetium

V.Korotkevich, A.Ryabov, S.Kruglov, N.Mikhailova, V.Volk, A.Vakhrushin (Siberian Group of chemical Enterprises, Seversk, Russia; SSC A.A.Bochvar All-Russian Scientific Research Institute of inorganic materials, Moscow, Russia)

 

2519          (16:45 17:05)

Behaviour and structure of 99Tc-species in solvent extraction systems of the nuclear fuel cycle

S. Tachimori, T. Yaita, S. Suzuki (Japan Atomic Energy Research Institute, Japan)

[Presentation Behaviour             Presentation Structure]

 

2520                    (17:05 17:20)

Mathematical model of kinetics of the technetium-catalysed oxidation of hydrazine reaction

P.Chibichik, A.Mashkin, V.Savinov (Federal State Unitary Enterprise "Mayak" Production Assosiation, Ozyorsk, Russia)

 

June 26 (Wednesday)

 

Other aspects of physics and chemistry of technetium and rhenium

 

                  Chairpersons:   V.Koltunov, S.Tachimori

 

2601                    (9:30 9:50)

Formation of Tc(IV) oxide colloids by bremsstrahlung irradiation of pertechnetate

T.Sekine, H.Narushima, H.Kudo, M.Lin, Y.Katsumura (Department of Chemistry, Graduate School of Science, Tohoku University; Nuclear Engineering Research Laboratory, School of Engineering, The University of Tokyo, Japan)

 

2602                    (9:50 10:05)

Possibilities of production of technetium short-lived radioactive isotopes

O.Maslov, S.Dmitriev, A.Sabelnikov (Joint Institute for Nuclear Research, Flerov Laboratory of Nuclear Reactions, Dubna, Russia)                     [Presentation in PPS-format]

  

2603                    (10:05 10:20)

Study of the sublimation and vaporization of alkali metal pertechnetates, MTcO4 (M= Na, K, Cs)

K.German, V.Peretrukhin (Institute of Physical Chemistry,RAS, Moscow, Russia)

[Presentation in PPS-format]

 

 2604                    (10:20 10:35)

NMR and quantum chemical study of cubic nanoparticles of technetium and its alloys with some noble metals supported at the ceramic matrix surfaces

K.German, N.Popova, V.Tarasov, Yu.Muravlev, Yu.Plekhanov (Institute of Physical Chemistry, RAS; Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow, Russia)

 

2605                    (10:35 10:50)

Extraction of oxoanions from alkaline solutions with quaternary ammonium base salts

A.Abramov, E.Galunin, V.Fedoseev (M.Lomonosov Moscow State University, Moscow, Russia)

 

                  Chairpersons:   K.German, K.Ito

 

2606                    (11:15 11:30)

Reaction in Re(VII) Sn(II) - HCl system

V.Koltunov, T.Gomonova (SSC A.A.Bochvar All-Russian Scientific Research Institute of inorganic materials, Moscow, Russia)

 

2607                    (11:30 11:50)

Evaporation of rhenium from nitric acid and sodium nitrate solutions at atmosphere pressure

K.Ito (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Japan)

 

2608                    (11:50 12:05)

Rhenium in non-traditional raw materials: determination, distribution, processing

A.Chekmarev, I.Troshkina (D.Mendeleyev University of Chemical Technology, Moscow, Russia)

 

2609                    (12:05 12:20)

Technology for rhenium recovery from solutions with extremely low concentrations

V.Volk, A.Vakhrushin, A.Besser (SSC A.A.Bochvar All-Russian Scientific Research Institute of inorganic materials; SSC State Scientific Research Institute of nonferrous metals GINTSVETMET, Moscow, Russia)

 

Radiopharmaceuticals of technetium and rhenium

                   Chairpersons:   V.Korsunsky, K.Hasimoto

 

2610          (14:30 15:00)

Radiopharmaceuticals on the base of technetium-99m in the next decade

G.Kodina (State Scientific Center Institute of Biophysics, Moscow, Russia)

 

2611          (15:00 15:15)

188W/188Re generator: for nuclear pharmacy or for hospital use?

R.Kuznetsov, S.Klimov, A.Pakhomov, O.Lepigina (State Scientific Center of Russian FederationResearch Institute of Atomic Reactors, Dimitrovgrad, Russia)

 

2612          (15:15 15:30)

Technetium-99m generator of high activity for nuclear medicine, clinical application with cold kits

A.Semyonova, D.Stepchenkov, G.Davydov, A.Sokolov (State Scientific Center of Russian Federation Institute of Physics and Power Engineering; Medical Radiological Research Center, RAMS, Obninsk, Russia)

 

2613          (15:30 15:45)

Obtaining molybdenum-99 in reactor IRT-T using resonance neutrons

V.Skuridin, E.Solodovnikov, E.Chibisov, E.Nesterov (Nuclear Physics Institute at Tomsk Polytechnic University, Tomsk, Russia)             [Presentation in PPS-format]

  

2614          (15:45 16:00)

Technetium-99 extraction generator with automatic control

V.Skuridin, A.Kolyasov, E.Chibisov, E.Nesterov (Nuclear Physics Institute at Tomsk Polytechnic University Tomsk, Russia)             [Presentation in PPS-format]

  

2615          (16:00 16:15)

Development of rhenium-188 extraction generator

V.Romanovski, D.Wester, S.Bartenev, M.Zykov, G.Kuznetsov, L.Shlkjar, G.Kodina, S.Erofeev, N.Usacheva, V.Buntsev, E.Kolobov (Khlopin Radium Institute, St.-Petersburg, Russia; Pacific Northwest Laboratory, Richland, USA; State Scientific Center - Institute of Biophysics, Moscow; Research and Development Institute of Construction Technology, Moscow, Russia)

 

                  Chairpersons:   G.Kodina, K.Tagami

 

2616                    (16:30 16:50)

Labeling of monoamine-monoamide dithiols (MAMA) ligand with generator-produced 188 Re using citric acid as a transfer ligand

K.Hashimoto, H.Matsuoka, K.Ogawa, T.Mukai, H.Saji (Department of Research Reactor, Japan Atomic Energy Research Institute; Graduate School of Pharmaceutical Sciences, Kyoto University, Japan)

 

2617          (16:50 17:05)

Study of complexing ability of HEDP with 188 Re

V.Petriev, V.Skvortsov, L.Bozadzhiev, L.Frolikova (Medical Radiological Research Center, RAMS, Obninsk, Russia)

[Presentation in PPS-format]

 

 

2618          (17:05 17:20)

Synthesis of 188Re-HEDP and 188Re-oxabiphor complexes

G.Kodina, E.Medvedeva, A.Sevastiyanova (State Scientific Center Institute of Biophysics, Moscow, Russia)

 

2619          (17:20 17:35)

Brain vessels scintigraphy with  TECHNETIUM-99m in recovery operation workers of the Chernobyl NPP accident consequences

N.Matveeva, M.Kaplan, O.Kruglova, O.Borgul (Medical Radiological Research Center, RAMS, Obninsk, Russia)

 

2620          (17:35 17:50)

Usefulness of Tc-99m Technetril and Tc-99m Karbomek in the diagnosis of thyroid medullar carcinoma

N.Olejnik, G.Davydov, P.Isaev, A.Ilyin (Medical Radiological Research Center, RAMS, Obninsk, Russia)

 

2621          (17:50 18:05)

Quality control of 99mTc-labelled human serum albumin for studies of the haemodynamics

N.Epstein, V.Yankova, V.Skvortsov, Yu.Kharitonov (Medical Radiological Research Center, RAMS, Obninsk, Russia; Moscow I.M. Sechenov Medical Academy, Moscow, Russia)

 

2622                    (18:05 18:20)

Indicator tubes for control of radiopharmaceuticals

E.Morosanova, N.Epstein (Lomonosovs Moscow State University; Medical Radiological Research Center, RAMS, Obninsk, Russia)

June 27 (Thursday)

 

10:00 21:00     Scientific Tour in Joint Institute for Nuclear Research and  Boat Trip To OUGLICH

 

15:30 17:00     ON-Board Session : Total Discussion - Technetium-99 in spent nuclear fuel and technetium-99m and rhenium-188 in nuclear medicine

 

17:00 17:30     Closing

  

Author Index

 

Addresses of participants

 

Photo Gallery

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Abstracts of the